Impact Factor (2025): 6.9
DOI Prefix: 10.47001/IRJIET
Liquid
crystals (LCs) are considered as the “fourth state of matter,” which can
display properties between crystals and isotropic liquids. LCs can be
classified into lyotropic liquid crystals (LLCs) and thermotropic liquid
crystals (TLCs), among which LLCs are a kind of self-assemblies formed by
amphiphile molecules in a given solvent within certain concentration ranges.
The structures and properties of LLCs can be tuned by the incorporation of
various kinds of additives, which represents an interesting and novel route for
realizing functional composites. Liquid crystalline materials typically involve
organic compounds and show a state of order intermediate between the familiar
crystalline lattices and those of isotropic liquids. Today, the word
“mesophase” is a more appropriate and meaningful description of this
intermediate state between crystal and liquid. Any organic liquid comprised of
nonspherical (either rod-like or discotic) molecules is, in theory, capable of
forming a mesophase, and about 0.5% of all pure organic compounds show liquid
crystalline behaviour. Liquid crystals may be divided into two broad
categories: thermotropic and lyotropic. Thermotropies have
temperature-dependent phase behaviour, while lyotropic exhibit
concentration-dependent phase behaviour. The former is typically a
one-component system, while the latter requires a solvent (e.g., water) plus
the liquid crystalline solute. In this monograph, emphasis will be given to
thermotropic systems. However, the results obtained from nuclear magnetic
resonance (NMR) spectra are quite similar in both types of liquid crystals.
Country : India
IRJIET, Volume 6, Issue 10, October 2022 pp. 101-106