Manufacture and Characterization of Porous Electrodes Using Graphite Materials

Abstract

The main challenge in meeting energy needs is balancing demand and supply in addition to the negative impact of energy use on the environment. Currently, most of the energy needs are supplied by fossil fuels whose sources are limited while their demand continues to increase. Efforts to overcome these challenges by developing environmentally friendly energy, one of which is hydrogen energy. One way to get hydrogen is through electrolysis. One of the components of electrolysis is the electrode. The effectiveness of the electrode depends on the surface area, pore structure, and pore distribution. In this paper, we discuss the process of making porous electrodes and determine the effect of porosity on resistivity and compressive strength. The process of making porous electrodes is carried out by adding a pore former with variations of 5%, 10%, and 15% of the total weight of graphite powder, then mixed with a mixer. A homogeneous mixture was added with polyvinyl alcohol as a binder at 4% wt. Powder that has been mixed with polyvinyl alcohol is molded in the form of a cylinder with a pressure of 28 MPa. The green compact was sintered at a temperature of 1200°C with a heating rate of 5°C/min, and a holding time of 1 hour. The sintered product was characterized by porosity, compression, SEM, and resistivity tests. The results showed that the highest compressive strength obtained was 6.809 MPa at a porosity of 27.47% and the highest resistivity was obtained at 0.1757 Ω. meter at a porosity of 39.41%.

Country : Indonesia

1 Sulistyo2 Sri Nugroho3 Djoeli Satrijo4 Hafiz Rahmat Fikri

  1. Mechanical Engineering, Diponegoro University, Semarang, Indonesia
  2. Mechanical Engineering, Diponegoro University, Semarang, Indonesia
  3. Mechanical Engineering, Diponegoro University, Semarang, Indonesia
  4. Mechanical Engineering, Diponegoro University, Semarang, Indonesia

IRJIET, Volume 6, Issue 11, November 2022 pp. 84-90

doi.org/10.47001/IRJIET/2022.611010

References

  1. Hosseini SE, Andwari AM, Wahid MA, Bagheri G. A review on green energy potentials in Iran. Renew Sustain Energy Rev 2013;27:533–45. https://doi.org/10.1016/j.rser.2013.07.015.
  2. Uysal S, Kaya MF, Demir N, Hüner B, Özcan RU, Erdem ÖN, et al. Investigation of hydrogen production potential from different natural water sources in Turkey. Int J Hydrogen Energy 2021;46:31097–107. https://doi.org/10.1016/j.ijhydene.2021.07.017.
  3. Ishaq H, Dincer I. Comparative assessment of renewable energy-based hydrogen production methods. Renew Sustain Energy Rev 2021;135:110192. https://doi.org/10.1016/j.rser.2020.110192.
  4. Miyamoto T, Hasegawa H, Mikami M, Kojima N, Kabashima H, Urata Y. Effect of hydrogen addition to intake gas on combustion and exhaust emission characteristics of a diesel engine. Int J Hydrogen Energy 2011;36:13138–49. https://doi.org/10.1016/j.ijhydene.2011.06.144.
  5. Rievaj V, Gaňa J, Synák F. Is hydrogen the fuel of the future? Transp Res Procedia 2019;40:469–74. https://doi.org/10.1016/j.trpro.2019.07.068.
  6. Chi J, Yu H. Water electrolysis based on renewable energy for hydrogen production. Cuihua Xuebao/Chinese J Catal 2018;39:390–4. https://doi.org/10.1016/S1872-2067(17)62949-8.
  7. Jamrozik A, Grab-Rogaliński K, Tutak W. Hydrogen effects on combustion stability, performance and emission of diesel engine. Int J Hydrogen Energy 2020;45:19936–47. https://doi.org/10.1016/j.ijhydene.2020.05.049.
  8. Givirovskiy G, Ruuskanen V, Ojala LS, Lienemann M, Kokkonen P, Ahola J. Electrode material studies and cell voltage characteristics of the in situ water electrolysis performed in a pH-neutral electrolyte in bioelectrochemical systems. Heliyon 2019;5:e01690. https://doi.org/10.1016/j.heliyon.2019.e01690.
  9. Sui J, Chen Z, Wang C, Wang Y, Liu J, Li W. Efficient hydrogen production from solar energy and fossil fuel via water-electrolysis and methane-steam-reforming hybridization. Appl Energy 2020;276:115409. https://doi.org/10.1016/j.apenergy.2020.115409.
  10. Liyanage D, Walpita J. Organic pollutants from E-waste and their electrokinetic remediation. INC; 2019. https://doi.org/10.1016/B978-0-12-817030-4.00006-1.
  11. Ursúa A, Gandía LM, Sanchis P. Hydrogen production from water electrolysis: Current status and future trends. Proc IEEE 2012;100:410–26. https://doi.org/10.1109/JPROC.2011.2156750.
  12. Dossow M, Dieterich V, Hanel A, Spliethoff H, Fendt S. Improving carbon efficiency for an advanced Biomass-to-Liquid process using hydrogen and oxygen from electrolysis. Renew Sustain Energy Rev 2021;152:111670. https://doi.org/10.1016/j.rser.2021.111670.
  13. Naimi Y, Antar A. Hydrogen Generation by Water Electrolysis. Intech 2018:1–18.
  14. Taspika AM. Manufacture of Porous Carbon Capacitor Electrodes From Pecan Shells (Aleurites Moluccana) As Capacitive Deionization System. J Fis Unand 2015;4:173–7. https://doi.org/10.25077/jfu.4.2.
  15. Yermukhambetova A, Berkinova Z, Golman B. Characterization of porous structure of graphite electrode with different packing densities. Mater Today Proc 2019;18:487–93. https://doi.org/10.1016/j.matpr.2019.06.235.
  16. Kim WY, Son DJ, Yun CY, Kim DG, Chang D, Sunwoo Y, et al. Performance assessment of electrolysis using copper and catalyzed electrodes for enhanced nutrient removal from wastewater. J Electrochem Sci Technol 2017;8:124–32. https://doi.org/10.5229/JECST.2017.8.2.124.
  17. Zhang B, Zhang SX, Yao R, Wu YH, Qiu JS. Progress and prospects of hydrogen production: Opportunities and challenges. J Electron Sci Technol 2021;19:1–15. https://doi.org/10.1016/J.JNLEST.2021.100080.
  18. Hayati S, Kurniasih Y. The Effect of Types Materials Electrode on the Efficiency of Silver Electrodeposition from Waste Photorontgen 2020:210–5.
  19. Afiah S. Study of Electrical Power Characteristics of Seawater With Voltaic Cell Principle and Electrode Corrosion Effects. Universitas Hasanudin, 2017.
  20. Tetra Olly, Aziz Hermansyah, Emriadi, Ibrahim Sanusi AA. Review: Supercapacitors Based on Activated Carbon and Ionic Solutions as Electrolytes. J Zarah 2018;6:39–46.
  21. Rahman DY. Efficiency Improvement Of Grafit / Tio2 Based Solar Cells Through Deposition Of Mineral Ions And Optimization Of Lioh Concentration In Polymer Electrolyte. Bandung Institute Technology, 2019.
  22. Simbolon AH. Performance of graphite/graphene, mn/graphite and mn/graphene as electrodes on primary stamped anode. Universitas Sumatera Utara, 2018.
  23. Drożdż E, Stachura M, Wyrwa J, Rękas M. Effect of the addition of pore former. J Therm Anal Calorim 2015;122:157–66. https://doi.org/10.1007/s10973-015-4693-y.
  24. Schmidt CG, Andersen KB, Stamate E, Kaiser A, Hansen KK. The role of pore-formers on grain interior and grain boundary conductivity in tape-cast porous sheets for electrochemical flue gas purification. J Ceram Sci Technol 2017;8:485–92. https://doi.org/10.4416/JCST2017-00024.
  25. Guler O, Bagci N. A short review on mechanical properties of graphene reinforced metal matrix composites. J Mater Res Technol 2020;9:6808–33. https://doi.org/10.1016/j.jmrt.2020.01.077.
  26. Callister WD, Rethwisch DG. Materials Science and Engineering An Introduction. 8th ed. New York: Wiley; 2011. https://doi.org/10.1063/1.2982126.
  27. Black JT, Kohser RA. De Garmo’s Materials and Processes in Manufacturing. John Wiley & Sons; 2020. https://doi.org/10.1201/b11792-12.
  28. Taer E, Afrianda A, Apriwandi, Taslim R, Agustino A, Awitdrus, et al. Production of activated carbon electrodes from Sago waste and its application for an electrochemical double-layer capacitor. Int J Electrochem Sci 2018;13:10688–99. https://doi.org/10.20964/2018.11.27.
  29. Sulistyo S. Impact of Ceramic Material Sintering Process on Mechanical Properties and Dimensions of a Product. Rotasi 2018;20:244. https://doi.org/10.14710/rotasi.20.4.244-248.
  30. Roulon Z, Missiaen J-M, Lay S. Shrinkage and microstructure evolution during sintering of cemented carbides with alternative binders. Int J Refract Met Hard Mater 2021;101:105665. https://doi.org/10.1016/j.ijrmhm.2021.105665.
  31. Aslam M, Kalyar MA, Raza ZA. Polyvinyl alcohol: A review of research status and use of polyvinyl alcohol based nanocomposites. Polym Eng Sci 2018;58:2119–32. https://doi.org/10.1002/pen.24855.
  32. Fergus J, Hui R, Xianguo L, Wilkinson D, Zhang J. Solid Oxide Fuel Cells: Materials Properties and Performance. 2008.
  33. Hedayat N, Du Y, Ilkhani H. Pyrolyzable pore-formers for the porous-electrode formation in solid oxide fuel cells: A review. Ceram Int 2018;44:4561–76. https://doi.org/10.1016/j.ceramint.2017.12.157.
  34. Prabowo A, Fadli A, Komalasari. The Effect of Corn Starch Addition on Bone Prototyping Using the Starch Consolidation Method. Jom FTEKNIK 2019;6:1–6.
  35. Rahayu I. Manufacture and characterization of ceramic membranes with variations of rice flour as an additive to the microfiltration process. J Sains Dan Terap Kim 2017;11:52. https://doi.org/10.20527/jstk.v11i2.4035.
  36. Wincewicz KC, Cooper JS. Taxonomies of SOFC material and manufacturing alternatives. J Power Sources 2005;140:280–96. https://doi.org/10.1016/j.jpowsour.2004.08.032.
  37. Kinasih TAP, Darmawan ADP, Ramadhan RF, Utama W. Analysis of the Effect of Porosity on Compressive Strength Values of Andesite Rocks Using Matlab-Based Hasselman And Ryshkewitch Regression Models. J Fis Indones 2020;24:131. https://doi.org/10.22146/jfi.v24i3.56549.
  38. Dele-Afolabi TT, Hanim MAA, Norkhairunnisa M, Sobri S, Calin R. Investigating the effect of porosity level and pore former type on the mechanical and corrosion resistance properties of agro-waste shaped porous alumina ceramics. Ceram Int 2017;43:8743–54. https://doi.org/10.1016/j.ceramint.2017.03.210.
  39. Sulistyo. Quality Control of Anode Solid Oxide Fuel Cell (SOFC) Through Porosity Control. Semin Nas Tah Tek Mesin Indones XIV 2015:7–8.
  40. Mahdiana N, Arifi E, Wisnumurti W, Firdausy AI. Effect of Void Ratio and Permeability of Concrete on the Compressive Strength of Porous Concrete with RCA. Rekayasa Sipil 2018;12:134–41. https://doi.org/10.21776/ub.rekayasasipil.2018.012.02.9.
  41. Sultan MA, Imran, Litiloly F. Correlation of porosity of concrete to average compressive strength. Teknol Sipil 2018;2:57–63.
  42. Ahmad SH, Jamil SM, Othman MHD, Rahman MA, Jaafar J, Ismail AF. Pore former addition in the preparation of highly porous anode using phase-inversion technique for solid oxide fuel cell. J Membr Sci Res 2019;5:268–73. https://doi.org/10.22079/JMSR.2018.74729.1162.
  43. Hakamada M, Kuromura T, Chen Y, Kusuda H, Mabuchi M. Influence of porosity and pore size on electrical resistivity of porous aluminum produced by spacer method. Mater Trans 2007;48:32–6. https://doi.org/10.2320/matertrans.48.32.
  44. Montes JM, Cuevas FG, Cintas J, Ternero F, Caballero ES. Electrical Resistivity of Powdered Porous Compacts. Intech 2018:1–24.
  45. Sun TM, Dong LM, Wang C, Guo WL, Wang L, Liang TX. Effect of porosity on the electrical resistivity of carbon materials. Xinxing Tan Cailiao/New Carbon Mater 2013; 28:349–54. https://doi.org/10.1016/S1872-5805(13)60087-6.