Nano-Technology and Its Applications in Water Purification

Abstract

Nanotechnology is the engineering and application of atoms, molecules, and particles whose sizes are on the nanometer scale (1-100 nm). Studies have shown that nanoparticles (NPs), most especially the nano metal oxides have improved and/or unusual physic chemical properties when compared with the corresponding bulk materials. Thus, these unique properties make NPs very useful in different field like medicine, electronics, biomaterials, energy production, water and wastewater treatment, etc. Different methods such as the gas phase synthesis (gas condensation processing, chemical vapour condensation, microwave plasma processing, and combustion flame synthesis), ball milling, co-precipitation, sol gel, micro emulsion, and surfactant have been widely reported in literature over the years for the production of NPs. There are few conventional technologies which are affordable and can be produced locally for effective removal of contaminants from water and wastewater. However, there are several challenges with regards to the cost and the removal efficiency of certain pollutants, most especially, the persistent organic pollutants and endocrine disruptors by these conventional technologies. Environmental nanotechnology vis nanotechnology and/or nanotechnology combined with conventional technologies are able to treat organic and inorganic contaminants to acceptable levels. There is currently intense scientific interest in nanotechnology for water and wastewater treatment; nevertheless, there are concerns about the toxicity and environmental impact of NPs. The application of nanotechnology for the removal of toxic pollutants such as the pharmaceutical and personal care products, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, phthalates, furans and dioxins, agrochemicals and pesticides, volatile organic compounds, viruses and bacteria, dyes, inorganic pollutants, etc., has been widely reported by several investigators in the field of nanotechnology. Interestingly, results have shown that environmental nanotechnology could be effectively utilized for the removal of organic and inorganic contaminants from drinking water, sewage, municipal, industrial and process wastewater.

Country : Iraq

1 Rahmah Ghazwan Sedeeq

  1. Department of Biophysics, College of Science, University of Mosul, Iraq

IRJIET, Volume 7, Issue 3, March 2023 pp. 59-71

doi.org/10.47001/IRJIET/2023.703008

References

  1. Shalini Chaturvedi, Pragnesh N. Dave.  Water Purification Using Nanotechnology an Emerging Opportunities. Chemical Methodologies 3(2019) 115-144.
  2. Droste R.L., Theory and practice of water and wastewater treatment. New York: Wiley, 1997.
  3. Shady Farah, Michael Nazarkovsky, Rajendra Pawar, Konda Reddy Kunduru. Nanotechnology for water purification: Applications of nanotechnology methods in wastewater treatment. Chapter • January 2017.
  4. WHO, 2014. Progress on Drinking Water and Sanitation. 2014 Update. Available from: http://apps.who.int/iris/bitstream/10665/112727/1/9789241507240_eng.pdf
  5. Qu, X., Alvarez, P.J.J., Li, Q., 2013a. Applications of nanotechnology in water and wastewater treatment. Water Res. 47, 3931–3946.
  6. Ali, I., 2012. New generation adsorbents for water treatment. Chem.Rev. 112, 5073–5091.
  7. Damià, B., 2005. Emerging Organic Pollutants in Waste Waters and Sludge. Springer, New York.
  8. Mohapatra, D.P., Brar, S.K., Tyagi, R.D., Picard, P., Surampalli, R.Y., 2014. Analysis and advanced oxidation treatment of a persistent pharmaceutical compound in wastewater and wastewater sludge-carbamazepine. Sci. Total Environ., 58–75.
  9. Gouma, P.I., Lee, J., 2014. Photocatalytic nanomats clean up produced water from fracking. Transl. Mater. Res. 1, 025002.
  10. Gupta S.K., Behari J., Kesari K.K. Asian J. Wat Envi. Pollu., 2006, 3:101.
  11. Chohan Z.H., Supuran C.T., Scozzafava A. J. Enzyme Inhib. Med. Chem., 2004, 19:79.
  12. Gupta, V.K., Nayak, A., 2012. Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles. Chem. Eng. J. 180, 81–90.
  13. Gupta, V.K., Agarwal, S., Saleh, T.A., 2012. Synthesis and characterization of alumina-coated carbon nanotubes and their application for lead removal. J. Hazard. Mater. 185, 17–23.
  14. Saleh, T.A., Agarwal, S., Gupta, V.K., 2012. Synthesis of MWCNT/MnO2 and their application for simultaneous oxidation of arsenite and sorption of arsenate. Appl. Catal. B 106, 46–53.
  15. Stackelberg, P.E., Furlong, E.T., Meyer, M.T., Zaugg, S.D., Henderson, A.K., Reissman, D.B., 2004. Persistence of pharmaceutical compounds and other organic wastewater  ontaminants in a conventional drinking-watertreatment plant. Sci.Total Environ. 329, 99–113.
  16. Ichinose N., Ozaki Y., Kashu S. Superfine particle technology. Springer, London, (Book) 1992.
  17. Stoimenov P.K., Klinger R.L., Marchin G.L. Klabunde K.J. Langmuir, 2002, 18:6679.
  18. Colvin V.L. Nat. Biotech., 2003, 21:1166.
  19. Diallo M.S., Savage N. J. Nano. Res., 2005, 7:325.
  20. Diallo M.S., Christie S., Swaminathan P., Johnson J.H., Goddard W.A. Environ. Sci. Technol., 2005, 39: 1366.
  21. B. Borrego, G. Lorenzo, J. D. Mota-Morales et al., “Potential application of silver nanoparticles to control the infectivity of Rift Valley fever virus in vitro and in vivo,” Nanomedicine: Nanotechnology, Biology and Medicine, vol. 12, no. 5, pp. 1185– 1192, 2016.
  22. R. S. Kalhapure, S. J. Sonawane, D. R. Sikwal et al., “Solid lipid nanoparticles of clotrimazole silver complex: an efficientnano antibacterial against Staphylococcus aureus and MRSA,” Colloids and Surfaces B: Biointerfaces, vol. 136, pp. 651–658, 2015.
  23. C.Krishnaraj, R. Ramachandran,K.Mohan, andP. T. Kalaichelvan, “Optimization for rapid synthesis of silver nanoparticles and its effect on phytopathogenic fungi,” Spectrochimica Acta—Part A: Molecular and Biomolecular Spectroscopy, vol. 93, pp. 95–99, 2012.
  24. I.Sondi and B. Salopek-Sondi, “Silver nanoparticles as antimicrobial agent: a case study on E. coli as a model for Gramnegative bacteria,” Journal of Colloid and Interface Science, vol. 275, no. 1, pp. 177–182, 2004.
  25. M. Danilczuk, A. Lund, J. Sadlo, H. Yamada, and J. Michalik, “Conduction electron spin resonance of small silver particles,” Spectrochimica Acta—Part A:Molecular and Biomolecular Spectroscopy, vol. 63, no. 1, pp. 189–191, 2006.
  26. K. I. Dhanalekshmi and K. S. Meena, “DNA intercalation studies and antimicrobial activity of Ag@ZrO2 core–shell nanoparticles in vitro,” Materials Science and Engineering: C, vol. 59, pp. 1063–1068, 2016.
  27. S. Prabhu and E. K. Poulose, “Silver nanoparticles: mechanism of antimicrobial action, synthesis, medical applications, and toxicity effects,” International Nano Letters, vol. 2, no. 1, p. 32, 2012.
  28. T. A. Dankovich and D. G. Gray, “Bactericidal paper impregnated with silver nanoparticles for point-of-use water treatment,”Environmental Science and Technology, vol. 45, no. 5, pp. 1992–1998, 2011.
  29. M. Rivero-Huguet and W. D. Marshall, “Reduction of hexavalent chromium mediated by micron- and nano-scale zerovalent metallic particles,” Journal of Environmental Monitoring, vol. 11, no. 5, pp. 1072–1079, 2009.
  30. V. Bokare, J.-L. Jung, Y.-Y. Chang, and Y.-S. Chang, “Reductive dechlorination of octa chloro dibenzo-p-dioxin by nanosized zero-valent zinc: Modeling of rate kinetics and congener profile,” Journal of Hazardous Materials, vol. 250-251, pp. 397–402, 2013.
  31. A.Fujishima and K. Honda, “Electrochemical photolysis of water at a semiconductor electrode,” Nature, vol. 238, no. 5358, pp. 37–38, 1972.
  32. G. Moon, D. Kim, H. Kim, A. D. Bokare, and W. Choi, “Platinum-like behavior of reduced graphene oxide as a cocatalyst on TiO2 for the efficient photocatalytic oxidation of arsenite,” Environmental Science & Technology Letters, vol. 1, no. 2, pp. 185–190, 2014.
  33. A.Janotti and C. G. Van deWalle, “Fundamentals of zinc oxide as a semiconductor,” Reports on Progress in Physics, vol. 72, no. 12, Article ID 126501, 2009.
  34. D. C. Reynolds, D. C. Look, B. Jogai, C.W. Litton, G. Cantwell, and W. C. Harsch, “Valence-band ordering in ZnO,” Physical Review B—CondensedMatterandMaterials Physics, vol. 60, no.4, pp. 2340–2344, 1999.
  35. Y. Chen, D. M. Bagnall, H.-J. Koh et al., “Plasma assisted molecular beam epitaxy of ZnO on c-plane sapphire: growth and characterization,” Journal of Applied Physics, vol. 84, no. 7, pp. 3912–3918, 1998.
  36. HaijiaoLu,  Jingkang Wang, Marco Stoller, Ting Wang, Ying Bao,  and Hongxun Hao .An Overview of Nanomaterials for Water and Wastewater Treatment. Hindawi Publishing Corporation Advances in Materials Science and Engineering Volume 2016, Article ID 4964828, 10 pages. http://dx.doi.org/10.1155/2016/4964828
  37. Yang, K., Xing, B., 2010. Adsorption of organic compounds by carbon nanomaterials in aqueous phase: polanyi theory and its application. Chem. Rev. 110, 5989–6008.
  38. Vukovic  G.D., Marinkovic  A.D., Cˇolic  M., Ristic  M.Đ., Aleksic  R., PericGrujic A.A., Uskokovic P.S. Removal of cadmium from aqueous solutions by oxidized and ethylenediamine-functionalized multi-walled carbon nanotubes. Chem. Eng. J. 157, 238–248. 2010.
  39. Musameh M., Hickey  M., Kyratzis  I.  Carbon nanotube-based extraction and electro chemical detection of heavy metals. Res. Chem. Intermed. 37, 675–689. 2011.
  40. Lau  W.J., Gray  S., Matsuura  T., Emadzadeh  D., Paul Chen  J., Ismail  A.F. A review on polyamide thin film nanocomposite (TFN) membranes: history, applications, challenges and approaches. Water Res. 80, 306–324. 2015.
  41. Liu L., Liu  J., Sun  D.D. Graphene oxide enwrapped Ag3PO4 composite: towards a highly efficient and stable visible-light-induced photo catalyst for water purification. Catal. Sci. Technol. 2, 2525–2532. 2012.
  42. Zhang  WX., Nanoscale iron particles for environmental remediation: an overview. J. Nanopart. Res. 5, 323–332. 2003.
  43. Khajeh M., Laurent  S., Dastafkan  K . Nanoadsorbents: classification, preparation, and applications (with emphasis on aqueous media). Chem. Rev. 113, 7728–7768. 2012.
  44. Kumar  S., Ahlawat  W., Bhanjana  G., Heydarifard  S., Nazhad  M.M., Dilbaghi N. Nano technology-based water treatment strategies. J. Nanosci. Nanotechnol. 14, 1838–1858. 2014.
  45. Gehrke, I., Geiser, A., Somborn-Schulz, A. . Innovations in nanotechnology for water treatment. Nanotech. Sci. Appl. 8, 1–17. 2015.
  46. Ramakrishna, S., Fujihara, K., Teo, W.-E., Yong, T., Ma, Z., Ramaseshan, R. Electrospun nanofibers: solving global issues. Mater. Today 9, 40–50.2006.
  47. Feng, C., Khulbe, K.C., Matsuura, T., Tabe, S., Ismail, A.F. . Preparation and characterization of electro-spun nanofiber membranes and their possible applications in water treatment. Sep. Purif. Technol. 102, 118–135. 2013.
  48. Lazar, M., Varghese, S., Nair, S. Photocatalytic water treatment by titanium dioxide: recent updates. Catalysts 2, 572. 2012.
  49. Li, Q., Mahendra, S., Lyon, D.Y., Brunet, L., Liga, M.V., Li, D., Alvarez, P.J.J. Antimicrobial nanomaterials for water disinfection and microbial control: potential applications and implications. Water Res. 42, 4591–4602. 2008.
  50. Hossain, F., Perales-Perez, O.J., Hwang, S., Roman, F. Antimicrobial nanomaterials as water disinfectant: applications, limitations and future perspectives. Sci. Total Environ. 466–467, 1047–1059. 2014.